In Episode 12, titled "Clash with the Black Cat Pirates! The Great Battle on the Slope!" , the story follows the Straw Hats as they defend Syrup Village from Captain Kuro's crew. Episode Summary
: Nami realizes the mistake, and the crew rushes to the other side of the island to intercept the invaders. [S1E12] Episode XII
: The episode concludes with the introduction of the Meowban (Nyaban) Brothers, Sham and Buchi, who prepare to fight Zoro. Key Details Information Saga East Blue Saga Arc Syrup Village Arc Original Air Date March 7, 2000 Manga Chapters Chapters 31, 32, and 33 In Episode 12, titled "Clash with the Black Cat Pirates
You can find more detailed scene breakdowns and character lists on the One Piece Wiki . In Episode 12